LrgpV1, Main, Exploration, bibRecord, 000D82

Flexible synthesis, structural determination, and synthetic application of a new C1-symmetric chiral ammonium betaine

Identifieur interne : 000D82 ( Main/Exploration ); précédent : 000D81; suivant : 000D83

Flexible synthesis, structural determination, and synthetic application of a new C1-symmetric chiral ammonium betaine

Auteurs : Daisuke Uraguchi [Japon] ; Kyohei Koshimoto [Japon] ; Takashi Ooi [Japon]

Source :

Chemical Communications [ 1359-7345 ] ; 2010.

RBID : ISTEX:561F3CBA49D64E8A9DA00DB85A73DF76B624B032

English descriptors

Abstract

A C1-symmetric chiral ammonium betaine has been developed, and its intramolecular ion-pairing structure in solid state and its catalytic performance to achieve the highly stereoselective Mannich-type reaction of 2-alkoxythiazol-5(4H)-ones are revealed.

Url:

https://api.istex.fr/document/561F3CBA49D64E8A9DA00DB85A73DF76B624B032/fulltext/pdf

DOI: 10.1039/b916627k

Affiliations:

Japon

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Le document en format XML

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<term>Betaine</term>
<term>Catalyst</term>
<term>Chem</term>
<term>Chiral</term>
<term>Chiral ammonium betaine</term>
<term>Chiral hplc</term>
<term>Chiral quaternary ammonium aryloxides</term>
<term>Crude mixture</term>
<term>Crystal data</term>
<term>Design concept</term>
<term>Diastereomeric ratio</term>
<term>Exible</term>
<term>Intramolecular</term>
<term>Intramolecular structure</term>
<term>Isomer</term>
<term>Mild conditions</term>
<term>Moiety</term>
<term>Nagoya university</term>
<term>Phenyl group</term>
<term>Probability level</term>
<term>Royal society</term>
<term>Side chains</term>
<term>Single crystal analysis</term>
<term>Stereoselective</term>
<term>Structural features</term>
<term>Substituents</term>
<term>Thermal ellipsoids</term>
<term>Uraguchi</term>
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<term>Chem</term>
<term>Chiral</term>
<term>Chiral ammonium betaine</term>
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<term>Chiral quaternary ammonium aryloxides</term>
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<term>Royal society</term>
<term>Side chains</term>
<term>Single crystal analysis</term>
<term>Stereoselective</term>
<term>Structural features</term>
<term>Substituents</term>
<term>Thermal ellipsoids</term>
<term>Uraguchi</term>
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<front><div type="abstract">A C1-symmetric chiral ammonium betaine has been developed, and its intramolecular ion-pairing structure in solid state and its catalytic performance to achieve the highly stereoselective Mannich-type reaction of 2-alkoxythiazol-5(4H)-ones are revealed.</div>
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Flexible synthesis, structural determination, and synthetic application of a new C1-symmetric chiral ammonium betaine

Flexible synthesis, structural determination, and synthetic application of a new C1-symmetric chiral ammonium betaine

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri